Anne Hathaway's 10 Best White Gowns…So Far

Before walking down the aisle in custom Valentino, the star had plenty of practice being the center of attention in bride-worthy dresses

GRECIAN & GORGEOUS

The Devil Wears Prada, but Anne looks positively angelic at the movie's 2006 Venice Film Festival premiere in a stunning draped column with a feminine, flowing sleeve accent, plus delicate gems.