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Before walking down the aisle in custom Valentino, the star had plenty of practice being the center of attention in bride-worthy dresses
Credit: Daniele Venturelli/WireImage
Updated: Friday Sep 28, 2012 | 06:00 AM EDT
By: Alex Apatoff
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The Devil Wears Prada, but Anne looks positively angelic at the movie's 2006 Venice Film Festival premiere in a stunning draped column with a feminine, flowing sleeve accent, plus delicate gems.
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